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Synthesis, Structure and Antiproliferative Activity of Three Gallium(III) Azole Complexes

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Synthesis, Structure and Antiproliferative Activity of Three Gallium(III) Azole Complexes
Zambouli, Dimitra
Vala, Vasiliki
Κυριακίδης, Δ.Α.
Zafiropoulos, Theodoros F.
Papaefstathiou, Giannis S.
Kortsaris, Alexandros H.
Zanias, Stergios
Raptopoulou, Catherine C.
Papazisis, Konstantinos T.
Άρθρο σε επιστημονικό περιοδικό
2010-07
As part of our interest into the bioinorganic chemistry of gallium, gallium(III) complexes of the azole ligands 2,1,3-benzothiadiazole (btd), 1,2,3-benzotriazole (btaH) and 1- methyl-4,5-diphenylimidazole (L) have been isolated. Reaction of btaH or btd with GaBr3 or GaCl3 resulted in the mononuclear complexes [GaBr3(btaH)2] (1) and [GaCl3(btd)2] (2), respectively, while treatment of GaCl3 with L resulted in the anionic complex (LH)2[GaCl4]Cl (3). All three complexes were characterized by single-crystal X-ray crystallography and IR spectroscopy, while their antiproliferative activities were investigated against a series of human and mouse cancer cell lines.
Ανόργανη χημεία (EL)
Inorganic chemistry (EN)
English
Hindawi Publishing Corporation
Bioinorganic Chemistry and Applications
Copyright © 2010 Stergios Zanias et al.
https://creativecommons.org/licenses/by-nc-nd/4.0/deed.el
National Hellenic Research Foundation (NHRF)
Helios - Repository of the National Hellenic Research Foundation (NHRF)



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